When you Sanctify, i.e., use a hero card (or stack of them), you will get a new saint attribute, might be gold, purple or blue. (I think gold heroes like Pompey are safe from getting white attributes.) Attributes you already have won't change or be otherwise affected, so no, a purple attribute will not become gold.
You might want to remove weak attributes to take a chance on getting a better one with a new sanctification. For example, a weak white attribute on a purple hero, or a weak blue attribute on a gold hero.



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